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Fine chemical materials

Fluorene-based acrylate

High refractive index, High heat resistance, Low birefringence
The acrylate of fluorene, for its three-dimentional structure of bulky cardo,
promises the properties that you have not seen in conventional acrylate.

Feature

High refractive index

High heat resistance

Low shrinkage by curing

Application

Application

Physical property data

  Acrylate monomer Mixture
Product name OGSOL
EA-0200
OGSOL
EA-0250P
(the 50% PGMEA dilution
OGSOL EA-0200)
OGSOL
EA-0300
OGSOL
GA-5060P
OGSOL
EA-F5710
Feature High refractive index
High heat resistance
High refractive index
High heat resistance
High flexibility
High heat resistance
High refractive index
High hardness
High refractive index
Solvent-free
The number of functional groups Bifunctional acrylate Bifunctional acrylate Bifunctional acrylate Bifunctional epoxy acrylate Formulation
(EA-0200/m-phenoxybenzyl acrylate)
Before
Curing
Refractive index
(589nm:D line, 25℃)
1.616 1.504 1.555 1.620 1.601
Solvent presence 5% toluene 50% PGMEA Solventless 40% PGMEA Solventless
Viscosity (25℃)
[mPa・s]
>100,000 <50 6,000-8,000 500-2,500 8,000-10,000
After
Curing
Refractive index
(589nm:D line, 25℃)
1.626 1.626 1.576 1.650 1.623
Tg(DSC)[℃] 211 211 17 228 127
Volume shrinkage[%] 0.5 0.5 0.7 No data 6.3
Water absorption[%] 0.08 0.08 2.6 No data 0.06

Total light transmittance

Total light transmittance

High transmittance in the visible light range makes the light sorce be effective.

Thermal stability evaluation

Thermal stability evaluation
Fluorene acrylate is excellent thermal stability and thermal yellowing due to rigid structure.
Product name 5% weight reduction temperature[℃]
EA-0200 416
EA-0300 382
GA-5060P 386
Bis-A diacrylate 375

Test conditon: TG-DTA(Measurement of weight reduction with heat)

Photopolymerization intiator: 3phr Irgacure 184

Integrated UV light intensity: 500mJ/cm2

Thickness: 2mm

Low shrinkage by curing

An improved example of cure shrinkage by blending a multifunctional acylate

An improved example of cure shrinkage by blending a multifunctional acylate

Fluorene aclyate has a feature such as low cure shrinkage by UV curing because of bulky 3D-sturucture.

∗ Values above are for references only, not guaranteed for the products.