Fluorene derivatives, optical plastic / Fine Materials Business

OGSOL acrylate : For photo-setting resin

The basic structure of OGSOL acrylate is bisaryl fluorene, with the advantages of a high refractive index, low cure shrinkage, and high transparency. Our lineup includes OGSOL EA, the standard type, and the OGSOL EA-F series whose viscosity is reduced to improve handling performance. As photoinitiators (or thermal polymerization initiators) are added to these products, it is easy to cure them by UV irradiation (or heating).

Advantages

  • High refractive index
  • High transparency
  • High thermostability
  • Low cure shrinkage rate
  • Low hygroscopicity

Example of usage

  • FPD related material
  • Optics adhesives
  • Antireflective coating
  • Resist material
OGSOL acrylate : For photo-setting resin Image

Physical properties (resin)

Product name OGSOL
EA-0200
OGSOL
EA-0500
OGSOL
EA-1000
OGSOL
EA-F5003
OGSOL
EA-F5503
(For reference)
Bis-A type acrylate
Advantages High refractive,
low shrinkage
High refractive,
flexibility
self-restoring High refractive,
low viscosity
High refractive,
low viscosity
Appearance Clear viscous liquid Clear viscous liquid Clear viscous liquid Clear viscous liquid Clear viscous liquid Clear viscous liquid
Solvent content Contained Contained Contained Not Contained Not Contained
Viscosity
(mPa · s : 25℃)
Before curing > 100,000 70,000-80,000 6,000-7,000 2,000-3,000 2,000-3,500 800-1,000
Refractive index (589 nm) 1.616 1.586 1.557 1.581 1.590 1,538
Hue (APHA) < 100 < 200 < 150 < 50 < 50 < 50
HAZE < 5 < 5 < 0.1 < 0.1 < 5
Transmittance rate
(% : 400nm)
After curing Film Per
(10μm)
98.4 99.9 98.8 98.8 98.8 98.8
Refractive index (589 nm) Film Per
(100μm)
1.626 1.600 1.573 1.607 1.614 1,562
Abbe number 22.7 26.6 31.5 28.6 25.8 37.7
Tg (℃) 211 62 21 94 115 69.7
Volume absorption coefficient (%) Bulk
(2mm)
1 2 3 3 4
Water absorption (%) 0.08 0.21 1.32 0.09 0.25

∗The data shown in the table are for the purpose of reference only. Listed values are not intended to provide any guarantee for products.

● Curing conditions
Photoinitiator : 3% of 'Irgacure 184' added
Based material : TAC (when film is created)
Irradiator : High voltage mercury lamp
UV integral light value : 360 mJ/cm2 (for film)
  : 2000 mJ/cm2 (for bulk)
● Measuring Method of physical properties
Transmittance rate   : 400 nm ; per 10μm
Transmittance rate of all light   : Complying with JIS K 7105
Tg (glass transition temperature)   : Measured by DSC
Volume absorption coefficient   : Calculated from density
    complying with JIS K 7112
Water absorption   : Complying with JIS K 7209
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